Gen Chem · Shared · C-RXN
Reaction Types & Balancing

Keep the atoms, and level the beam.

A chemical reaction is not a magical creation; it is an atomic remodeling project. Bonds break, elements separate, and new structures assemble—but the starting building blocks never vanish. The Law of Conservation of Mass dictates that every single atom present before a reaction must remain afterward. To model this, we balance chemical equations with molecular coefficients. In this lesson, you will learn to categorize chemical changes into five distinct patterns and balance molecular equations visually.

Na Na Cl Cl 2 Na + Cl₂ Products Form Here LEDGER:     Sodium (Na): 2 on left • 2 on right    •    Chlorine (Cl): 2 on left • 2 on right
Rearranging Electrons Transferring... LEDGER:     Sodium (Na): 2 on left • 2 on right    •    Chlorine (Cl): 2 on left • 2 on right
Reactants Consumed Na⁺ Cl⁻ Cl⁻ Na⁺ 2 NaCl (crystal) LEDGER:     Sodium (Na): 2 on left • 2 on right    •    Chlorine (Cl): 2 on left • 2 on right

the atoms are rearranged, not created or destroyed · ledger counts stay identical

Alignment
HS-PS1-2, HS-PS1-7 Categorize chemical changes and balance equations to support mass conservation (PS1-2.2, .3 targets).
Objective
Identify synthesis, decomposition, combustion, single replacement, and double replacement reactions (recognizing acid-base reactions as a double replacement special case), and balance equations using a visual balancer.
Scope
Five main reaction categories plus acid-base recognition, coefficient balancing rules, atomic conservation.

Core Claims

  • Reaction Types: Chemical reactions are categorized into distinct classes based on rearranging patterns (synthesis, decomposition, single-replacement, double-replacement, combustion, and acid-base).
  • Law of Conservation: Atoms are never created or destroyed; every single atom in the reactants must appear in the products.
  • Balancing Rules: Adjust coefficients (moles) to level the atomic inventory. Subscripts define chemical identity and must never be altered.

Synthesis Blueprint (A + B → AB)

A + B

Retrieval Checklist

  • Classify a reaction into one of the six standard types.
  • Balance chemical equations by adjusting coefficients.
  • Verify atom conservation on both sides of the arrow.

Five blueprints of rearrangement.

Rather than memorizing millions of unique chemical reactions, chemists categorize reactions into a few core blueprints. By looking at how the reactants are combined, you can predict what kind of products will form.

Five Reaction Blueprints

Synthesis

A + B → AB

Example: 2 Mg + O₂ → 2 MgO

Signature: Two things walk in, one thing walks out. Separate elements or simple compounds combine to make a single final compound.

Decomposition

AB → A + B

Example: 2 H₂O₂ → 2 H₂O + O₂

Signature: One reactant, multiple products — usually needs heat, electricity, or a spark to kick it apart.

Single Replacement

A + BC → AC + B

Example: Zn + CuSO₄ → ZnSO₄ + Cu

Signature: A lone element on each side of the arrow — one element shoves another out of its compound to take its place.

Double Replacement

AB + CD → AD + CB

Example: AgNO₃ + NaCl → AgCl + NaNO₃

Signature: Two compounds swap partners — positive ions change negative partners. Often watch for a solid precipitate dropping out of solution.

Combustion

fuel + O₂ → CO₂ + H₂O

Example: C₃H₈ + 5 O₂ → 3 CO₂ + 4 H₂O

Signature: O₂ on the left, CO₂ and H₂O on the right. If those three appear and heat is released, it is combustion, full stop.

Acid-Base Neutralization

acid + base → salt + water

Example: HCl + NaOH → NaCl + H₂O

Signature: An H-first compound (acid) meets an -OH compound (base); water (H₂O) always forms along with an ionic salt.

Naming this pattern "neutralization" is beyond this course's assessment boundary. You won't be asked to classify a reaction as neutralization specifically — but you should always recognize it as a double replacement underneath.

Practice classifying reactions

Adjust coefficients, lock the subscripts.

To conserve atoms, we might be tempted to change the subscripts inside formulas. Never do this. Subscripts define the chemical identity of a substance. If you change the subscript of water (H2O) to H2O2 to get more oxygen, you are no longer modeling water—you are modeling hydrogen peroxide, a corrosive bleach. You cannot change the recipe ingredients to balance the scale.

Instead, we adjust the coefficients (the numbers placed in front of formulas). A coefficient scales the entire molecule. Placing a "2" in front of H2O (2 H2O) means you have two distinct water molecules, doubling the counts of both hydrogen and oxygen atoms without changing what the substance is.

Walkthrough: balancing methane combustion

CH₄ + O₂ → CO₂ + H₂O Element Left Right Carbon (C) 1 1 Hydrogen (H) 4 2 Oxygen (O) 2 3
Drawing boundaries

Think of each compound as being inside a sealed plastic box. You can buy more boxes (coefficients), but you cannot open the box to alter the atoms inside (subscripts).

Balance the beam. Conserve the atoms.

Select a chemical equation. Use the plus and minus buttons to change the coefficients. Watch the molecule drawings populate the balance beam. When the atom counts match on both sides, the beam will level out.

Choose Reaction to Balance:
Reactant Coefficients
Product Coefficients
Atom Count Ledger Unbalanced

Predict the coefficients.

Say it back.

Fill in the blanks to lock in the core terms. Matches are case-insensitive.

Balancing & Types Vocabulary

Fill in the terms.

Why lock the subscripts?

Balance a thermal decomposition.

Gen Chem · HS-PS1-7 · constructed response [3 marks]
Why This Matters

Automobile airbags rely on precise stoichiometry. In a crash, a sensor triggers the rapid decomposition reaction of solid sodium azide (NaN₃). Balancing the equation shows how a small, dense pellet of reactant rapidly yields a massive volume of nitrogen gas (N₂) in milliseconds, cushioning the impact.